Qualifier Liudmila Samsonova continued what she described as an "unbelievable" run by upsetting Victoria Azarenka to seal a place in the bett1open final in Berlin.
The world number 106 reached her first career final by beating two-time major champion Azarenka 6-4 6-2, having impressively seen off Madison Keys in the last eight.
It took just 66 minutes for Samsonova to win as she put on a powerful display of hitting on Saturday, firing down 11 aces.
The 22-year-old did not lose serve in the match and is the first qualifier to reach a WTA 500 final this season.
"It's all incredible for me, it's so new, and I'm very happy for it," Samsonova said amid a week that will give her a rankings surge.
"It’s unbelievable for me. It is the most important [week] of my life up to this moment.
"I'm sure it’s going to be a tough match because [Bencic] plays very good on this surface, and she's a good player. I will try to do my best and focus on my game, and we will see."
Fifth seed Bencic battled to a 7-5 6-4 victory over Alize Cornet in her last-four clash and will go into the final as favourite.
While the win came in straight sets, it was a hard-fought encounter, with Bencic winning all four of her break points while Cornet forced 10 but only converted two, which proved to be the difference.
Bencic, who will be encouraged ahead of Wimbledon, has now made four grass-court finals in her career and will seek her first WTA Tour title since October 2019 on Sunday.
The Swiss star, who had 29 winners and just 19 unforced errors against Cornet, lost to Iga Swiatek in Adelaide earlier this year in her only final appearance since that last title.
"I always try to play as many tournaments on grass as possible because I just love the surface," Bencic said.
"Of course it gives me a lot of confidence. It's always great to have this confirmation on grass that it is working well."
Djokovic thrilled by prospect of 'one last dance' with Nadal
Novak Djokovic is thrilled by the prospect of meeting Rafael Nadal for "one last dance" at the Paris Olympics, if the Spaniard overcomes an injury setback to feature at Roland-Garros.
Thursday's men's singles draw saw Djokovic paired with Australia's Matthew Ebden in the first round, with Nadal taking on Marton Fucsovics.
The legendary duo – who have won 46 grand slam singles titles between them – will meet in the second round if they both advance through their openers this weekend.
Djokovic and Nadal have previously faced off on 59 occasions, with the Serbian winning 30 of those contests but losing four of the last six, the most recent being a Nadal victory in four sets in the 2022 French Open quarter-finals.
Nadal's participation at the Games was thrown into doubt when his coach Carlos Moya said he had suffered a "setback" on Thursday and required 48 hours of rest.
If Nadal – who is widely expected to retire later this year – does make the tournament, Djokovic is looking forward to the prospect of facing him for a 60th time.
"Obviously he hasn't played much. His ranking dropped, so there was always going to be that possibility of me meeting him in an early round and there we go," Djokovic said.
"It's going to be a spectacle, definitely, if we get to meet. We will spread some fireworks on the court, like the good old times.
"I hope we get to meet because it will probably be one last dance for the both of us."
Djokovic is set to appear at his fifth Olympics in the French capital, the joint-most by any male player since the sport returned to the Games in 1988 (with Yen Hsun Lu).
He is the player with the most matches played (19) and joint-most matches won (13, level with Roger Federer) at the Olympics since 1988.
However, his best result at the Games remains a Bronze medal at Beijing 2008, when he was beaten by eventual gold medallist Nadal in the semi-finals.
Djokovic lost the bronze medal match to Pablo Carreno Busta at the delayed Tokyo Games three years ago, also losing to Juan Martin del Potro at both London 2012 and Rio 2016.
Linette dominates first all-Polish WTA final to win Prague Open
Magda Linette rounded off her Olympic preparations in style as she claimed her third WTA title with a comfortable win over Magdalena Frech at the Prague Open.
Linette, who beat Viktoriya Tomova and Linda Noskova on her way to the final, won in straight sets 6-2 6-1 as she now heads to Paris to face Mirra Andreeva.
The world number 41 was in the ascendency from the off, forcing a break in the fourth game and never looking back.
Despite the best efforts of Frech, who saved one set point, Linette continued to apply the pressure and another break put her a set up.
Linette would again break in the fourth game of the second set, winning three games on the bounce to secure her first career win over her compatriot.
Data Debrief: Linette prevails in first all-Polish affair
The final in Prague between Linette and Frech was the first all-Polish WTA level final in the Open Era.
Linette's triumph over her opponent was her first, having lost in the pair's previous encounter in Saint-Malo back in 2022.
During the contest, the world number 41 gave nothing away, saving all four of the break points she faced while converting three of the seven she had against Frech.
Nadal suffers injury 'setback' as Olympics participation thrown into doubt
Rafael Nadal may be facing another injury setback at the Paris Olympic Games after his coach warned over the Spaniard's fitness.
The 22-time major champion is widely expected to retire at the end of this year, though is preparing for a final swansong at Roland-Garros, where he has won 14 titles.
Nadal is set to play in the singles and doubles tournaments of the Olympics, partnering current French Open and Wimbledon champion Carlos Alcaraz for the latter competition.
Yet his participation has become doubtful after coach Carlos Moya confirmed Nadal had cancelled his training session on Thursday due to a hamstring issue.
"It was a setback and we decided that today Rafa would rest and not train to recover," Moya said, as quoted by Spanish journalist Rafael Plaza.
"We are going to give ourselves 48 hours, we have to wait."
The 38-year-old is reportedly feeling soreness in both his left and right hamstring having pulled out of a scheduled practice session with Alexander Zverev.
Alcaraz had been partnering Nadal throughout the week during training on the clay courts of Paris, though the veteran's feature has now been thrown under a cloud of doubt.
Nadal is one of just two players to have won Olympic gold in both singles and doubles since the sport returned to the Games in 1988, doing so at Beijing 2008 (singles) and Rio 2016 (doubles).
In the singles in the French capital, Nadal has been drawn against Hungary's Marton Fucsovics in the opening round, and the prize could be a second-round date with long-term rival Novak Djokovic.
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