Jon Rahm was the major casualty from the WGC Match Play on Friday as Scottie Scheffler, Rory McIlroy and Patrick Cantlay all advanced with perfect records.
The Spanish second seed was dumped out after losing 5 and 4 to 2021 WGC Match Play winner Billy Horschel in their final Group 2 match at the Austin Country Club in Texas.
Horschel went 1-up with a par on the second hole and never relinquished the lead, with Rahm failing to register a birdie throughout the day's play.
The 36-year-old American pulled away with birdies on the 10th and 11th holes followed by a 21-foot birdie putt on the 14th to clinch a spot in the round of 16 against Cameron Young.
Horschel progressed in a tight group with a 2-0-1 record ahead of Rickie Fowler (2-1-0), Rahm (1-2-0) and Keith Mitchell (0-2-1).
Top seed and reigning champion Scheffler advanced after beating Tom Kim 3 and 2 to round out a 3-0-0 group stage record.
Kim came out strong with birdies on the first two holes to go 2-up, but Scheffler rallied back immediately winning three of the next four holes.
Third seed McIlroy topped Group 3 unblemished after beating Keegan Bradley 3 and 2, while fourth seed Cantlay beat Brian Harman 2 and 1 to top Group 4 with a 3-0-0 record.
Kurt Kitayama won a three-way sudden death playoff over Tony Finau and Adrian Meronk to progress atop Group 10.
Canadian Mackenzie Hughes produced an upset to advance via Group 12 from Taylor Montgomery who he beat 6 and 4. Jordan Spieth, who beat Hughes on Thursday, missed out after losing to Shane Lowry 2 and 1.
J.J. Spaun also pulled off a surprise by topping Group 11 with a 3-0-0 record, downing Min Woo Lee 2 and 1 to seal his progress.
Max Homa, Xander Schauffele, Andrew Putnam, Matt Kuchar, Sam Burns, Lucas Herbert, J.T. Poston, Jason Day and Young also all progressed into Saturday's last 16 knockout stage.
Rahm sets sights on Ryder Cup but refuses to pay DP World Tour fines
Jon Rahm has no intention of paying the fines dealt his way by the DP World Tour, as he reiterated his desire to play at the Ryder Cup.
Rahm, who starred as Europe beat the United States in Rome last year to regain the Ryder Cup, moved to LIV Golf in February.
The Spaniard's participation in next year's Ryder Cup, which will be held in New York, remains in doubt.
Rahm was slapped with fines for playing in LIV tournaments that clashed with DP World Tour events without having requested permission.
If he does not play in three more DP World Tour tournaments before the end of the season in November, he will not be eligible to play at the Ryder Cup.
However, despite Rahm entering the Spanish Open, Dunhill Links Championship and Andalucia Masters, he will be unable to play until he pays his fines, something the 29-year-old does not plan on doing.
"I'm not a big fan of the fines. I don't intend to pay the fines and we keep trying to have a discussion with them about how we can make this happen," he said.
"I intend to play in Spain. Whether they let me play or not is a different thing."
Former European captain Padraig Harrington has limited sympathy for Rahm.
"I'm a stickler for the rules," he said.
"I'm friends with Jon but if the rules are written down, that's just the way it is. The Ryder Cup is bigger than just the match. It is the backbone of the European Tour.
"The European Tour doesn't have a lot of leverage to get players to come back across and play here. The Ryder Cup is the carrot that we use to get people to come back.
"It is a very tough situation for Luke Donald and the Ryder Cup but if the 12th guy who qualifies by sticking to the rules gets bumped out, he's not going to be happy if somebody else has not stuck to the rules. We can't forget that person."
McIlroy hoping for 'solution' to latest PGA-PIF talks
Rory McIlroy hopes there will be a "solution" from this week's scheduled talks between the PGA Tour and Saudi Arabia's Public Investment Fund (PIF).
Tiger Woods is reportedly among a number of PGA Tour representatives in New York for discussions with representatives from PIF, which funds the LIV Golf tour.
Negotiations for a deal that would inject over $1billion from PIF into PGA Tour Enterprises - launched by the tour and Strategic Sports Group as the new for-profit entity - began over a year ago,
McIlroy recently revealed his frustration at the lack of progress, but is hopeful the ongoing issues will soon be resolved.
"I think everyone in the game would love there to be one [a resolution]," the world number three told BBC Sport NI.
"A solution is hard to get to because there are different interests and people want different things. There's going to have to be compromise on both sides but hopefully they're the things they're talking about in those meetings.
"I'm hopeful and hopefully we'll be hear some good news in the foreseeable future where things start to come back together."
McIlroy was speaking ahead of this week's Irish Open at Royal County Down, where he hopes to deal with the pressure of performing on home soils.
"I've had to learn over the years how to manage my week when I come home," he added. "I'm trying so hard to perform in front of the home fans, but then if I push too hard, it's detrimental to my game.
"It's about managing all those emotions and getting lost in my own little world, and not trying to do anything I wouldn't normally do.
"Just go out there and play the best golf that I can and not get too frustrated when things don't go my way. If I can do that then I think I'll be OK.
"It would be extra special [to win here]. After everything that went on this summer and being so close to winning the US Open and being close at the Olympics as well, it would be a nice way to forget about those things and move on."
Rose wants Rahm to make himself eligible for Ryder Cup
Justin Rose has urged Jon Rahm to make sure he is eligible for the Ryder Cup next year.
The Spaniard, who plays on the LIV circuit, needs to play three events on the DP World Tour before the end of the season in November to be available for selection.
The Spanish Open looks to be the most likely solution for the two-time major winner, but he has not yet submitted an entry, which would need to be in by September 12.
If he fails to meet the requirements needed for his tour membership, Luke Donald will not be able to call on him, even for one of the wild card spots, as Europe look to defend their trophy at Bethpage next September.
Rose believes not having Rahm in the team would be a huge blow to Team Europe's chances in New York last year, but understands the Tour's need to enforce the regulations.
"No matter where the world rankings say he is or the golf that he is competing against, we know what a great player he is," Rose said, speaking after an event at Brocket Hall.
"My point is you want him on the team. There is a pathway for him to play the Ryder Cup if he wants it.
"I think that's all the DP World Tour can do, and they have their interests to protect, and I still think that it is a doable situation should the player want to choose to do it."
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