Emiliano Buendia and Douglas Luiz condemned Tottenham to a 2-0 defeat at the hands of Aston Villa in their opening match of 2023.
Antonio Conte's side missed the chance to return to the top four as their opponents ended a run of five successive Premier League defeats in London.
Villa, who also claimed a first clean sheet in the English capital in 14 attempts, struck twice after the break at the Tottenham Hotspur Stadium with neat finishes from Buendia and Douglas Luiz.
Tottenham remain fifth in the table after suffering only a second loss from their last nine matches played on New Year’s Day.
The visitors enjoyed most of the possession during the early stages of the first half.
A swift counter culminated in Ollie Watkins drilling a low 20-yard effort narrowly wide of the near post, while an important Boubacar Kamara block denied Matt Doherty at the other end after the Tottenham full-back’s strong run into the box.
Villa then had Ashley Young to thank five minutes before the break, the full-back showing brilliant reflexes to clear Harry Kane’s goalbound header off the line.
But the visitors snatched the lead within five minutes of the restart. Watkins reacted quickly after Hugo Lloris spilled Douglas Luiz's fierce long-range effort, the England striker teeing up Buendia to slot home.
The roles almost reversed in the 62nd minute when Buendia's neat through-ball found Watkins, who was blocked by the recovering Doherty.
Villa did grab the second goal to seal the points 17 minutes from time, Douglas Luiz latching onto John McGinn's precise pass before neatly beating Lloris from close range.
'We weren't efficient' - Marquinhos bemoans PSG profligacy after Champions League exit
Marquinhos believes Paris Saint-Germain paid for their profligacy after suffering Champions League semi-final heartbreak against Borussia Dortmund.
Mats Hummels' second-half header from a Julian Brandt corner - the only goal at Parc des Princes - wrapped up a 2-0 aggregate victory for the Bundesliga side, who advanced to their third final and first since 2013.
Meanwhile, PSG's wait to land the elusive European crown goes on, despite a whopping 44 shots across the two legs, while they also struck the woodwork on six occasions - their overall tally of 14 the most recorded by a team during a single campaign.
Indeed, Luis Enrique's side failed to find the net in a home match for the first time since their 0-0 draw with Lorient in their first Ligue 1 match of the season, as their hopes of completing the treble vanished for another year.
"We lacked efficiency," Marquinhos told Canal+. "They scored two goals from corners and a through ball that we had worked on. We had to defend better. These are small details.
"We created chances, a lot more than them. We weren't efficient. They were efficient, they scored two goals and won both matches."
But despite the disappointment, the PSG skipper urged his team-mates to focus on the positives from their run to the semi-finals.
They recovered from a disappointing 4-1 defeat against Newcastle United to finish second behind Dortmund in Group F, before overturning a 4-2 aggregate deficit to deny Barcelona in the quarter-finals.
"There are a lot of things to take away from this competition," Marquinhos added. "At the beginning of the season, no one believed that we would get this far. We've overcome a lot of obstacles, we shouldn't throw everything away now just because we're eliminated.
"You have to remember that it's a new team, with a new coach. There are some positives to bring back for next season. We wanted to go to Wembley for the fans and our families.
"You have to stay calm after the elimination. It's very hard. We've come very close. We had to win tonight and be more efficient."
Veteran campaigner Hummels the hero as fine margins cost PSG
Mats Hummels was Borussia Dortmund's hero on Tuesday, as his goal sent the Bundesliga side into the Champions League final.
Hummels' second-half header was the difference as BVB won 1-0 on the night against Paris Saint-Germain in the French capital, and a 2-0 win on aggregate.
The average age of PSG's starting XI was 24 years and 157 days, which was the youngest starting XI to be named in a Champions League semi-final since Arsenal in May 2009.
Yet it was a veteran campaigner in Hummels who was decisive.
His excellent header was the centre-back's first goal in the Champions League for Dortmund since February 2013.
At the age of 35 years and 143 days, Hummels became the third oldest player to score a Champions League semi-final goal, after Ryan Giggs in 2010-11 (37y 148d) and Edin Dzeko last season (37y 54d).
It was only his fifth goal in the competition, and Hummels' first in 42 games, since he netted for Bayern Munich against Ajax in October 2018.
PSG will ultimately rue the fine margins as their Champions League curse continues.
Kylian Mbappe had five shots, but could not wield his usual influence on proceedings, other than when he hit the crossbar - one of four PSG attempts that struck the woodwork.
Indeed, PSG hit the frame of the goal 14 times throughout their campaign. This is the most on record (since 2003-04) by any team in a single season. Six of these came in this tie.
PSG amassed 3.2 expected goals. This was just the fourth Champions League game on record (since 2010-11) in which a team managed at least 3.0 xG but has failed to score.
This is just the second time a team has won both legs of a Champions League semi-final tie by a 1-0 scoreline – Dortmund were also the other occasion, against Manchester United in 1996-97.
Dortmund have now reached the Champions League final for the third time. The last time they did so was also the last time the showpiece was played at Wembley Stadium (2013), when they lost to Bayern, who they could yet meet again this time around.
Al Ahli 1-2 Al Hilal: Malcom saves league leaders' winning streak
Malcom’s stunning solo goal finished Al Hilal’s second-half comeback to earn a 2-1 win over Al Ahli in the Saudi Pro League on Monday.
The forward started his run from inside his own half before slotting in the winner, after teeing up Aleksandr Mitrovic for the equaliser just after the interval.
Feras Al Brikan had given Al Ahli the lead in the 30th minute, but the hosts could not hold onto it against the league leaders.
Al Hilal continue their unbeaten league campaign to a 30th match, moving 12 points clear at the top of the table, while Al Ahli remain in third, now 22 points off the AFC Champions League spot.
Data Debrief
Malcom was one of Al Hilal's most influential players; as well as playing a hand in both goals, he had the joint-most shots (five), and the joint-most shots on target (two), and created two chances for his team.
Al Ahli also struggled to cope with Mitrovic's threat, as the Serbian created an xG of 0.61 from his five shots, having 11 touches in the opposition box.
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