Liverpool can seal progression to the Champions League last 16 when they play on Wednesday, but Barcelona could see their exit confirmed from Europe's top competition.
Jurgen Klopp's Reds make the trip to face Ajax in Group A knowing they are guaranteed a spot in the Europa League at the very least – and simply avoiding defeat would guarantee their place in the Champions League knockout stages.
It is a more dicey affair for Xavi's Barca, however, as they welcome Bayern Munich to Camp Nou in Group C knowing a loss would spell the end of their journey. Even a win will not be enough if Inter defeat Viktoria Plzen.
Tottenham will hope to keep their noses in front in Group D, with Marseille and Sporting CP just a point behind, while Atletico Madrid have work to do in Group B.
Stats Perform previews Wednesday's eight matches by picking through the Opta data.
Ajax v Liverpool
Ajax have made for generous opponents for Liverpool of late, losing their last three against the Reds in the Champions League. Only Juventus (four, 1997-2004) and Real Madrid (seven, 2010-2019) have previously won four in a row against Ajax in the European Cup or Champions League.
Yet Ajax remain the last Dutch side to achieve a home win against Liverpool, albeit that was back in 1966, with the Premier League side unbeaten in seven subsequent trips to the Netherlands.
Liverpool's countrymen have also made hay, as Ajax have won just one of their last eight home European matches against English teams, beating Manchester City in October 2012.
With or without another strong result, this will be an historic occasion for Liverpool and Klopp, who will match Rafael Benitez's 62 Champions League matches in charge of the Reds, who bring up 150 games in the competition.
Barcelona v Bayern Munich
Needing a win, Barca might have hoped to face any team but Bayern, who have a record three Champions League away wins at the Blaugrana. Along with Juventus and Real Madrid, they are one of three teams to have won more matches at Barca than they have lost.
Home and away, Barca have lost nine of their 12 Champions League matches against Bayern, including the past five in a row.
In fact, if Bayern win again, they will match Madrid's record of 10 wins against a single opponent in the competition – Madrid's dominance coming against Bayern.
Although Bayern are already through, they are seeking a fourth home-and-away double against Barca in a Champions League season (also 1998-99, 2012-13 and 2021-22). Dynamo Kyiv (in 1997-98) are the only other team to beat Barca twice in the same campaign even once.
Tottenham Hotspur v Sporting CP
Sporting won 2-0 against Tottenham in Portugal in what was the sides' first meeting, but they have a dismal record in England, with two victories in 15 attempts away to English sides.
Spurs have won six of their seven home European matches against Portuguese opposition, only losing to Benfica in the 2013-14 Europa League.
Both of Tottenham's wins in this campaign have come at home, where Antonio Conte is bidding to become just the second Spurs coach to win each of his first three at home in the Champions League – after Harry Redknapp.
He and Tottenham will know they must keep their focus early and late; Sporting's last three Champions League goals have come in either the first or last minutes of the match, netting twice in second-half stoppage time in the reverse fixture.
Atletico Madrid v Bayer Leverkusen
Atletico have not lost at home to Leverkusen in their prior four such matches, winning two and drawing two, but the Bundesliga team have started to turn the tide, winning two in a row against them in the Champions League.
That strong home record applies whenever Atletico face German opposition, though, as Borussia Dortmund were the last Bundesliga visitors to win there in 1996. Atleti are unbeaten in 11 since.
Diego Simeone needs his team to rediscover their scoring touch, having gone three without a goal in the Champions League.
That is their worst run under Simeone. Only once in the competition have Atletico gone four without netting, back in 2009 under Abel Resino.
Other fixtures:
Club Brugge v Porto
21 – Club Brugge goalkeeper Simon Mignolet has saved all 21 of the shots on target he has faced in the Champions League this season. He has prevented a competition-leading 4.9 goals, according to expected goals on target data.
4 – Four of Porto's last seven Champions League goals have come from the penalty spot.
Inter v Viktoria Plzen
12 – Inter have scored 12 of their last 14 Champions League goals in the second halves of matches. All three against Barca last time out came after the interval – only the third time an away team has netted three second-half goals at Camp Nou in this competition.
28 – Plzen have averaged just 28 per cent of the possession in the Champions League this season, the lowest average by a team in a single season since Opta data collection began in 2003-04.
Napoli v Rangers
4 – Napoli have won all four of their matches in the Champions League this season and could become the first Italian side to win their opening five games in a single campaign since Juventus in 2004-05.
12 – No goalkeeper has faced more shots on target (29) or conceded more goals (12) than Rangers' Allan McGregor in the Champions League this season. Indeed, he has only kept four clean sheets in 21 appearances in the competition overall.
Eintracht Frankfurt v Marseille
50 – Eintracht Frankfurt's Mario Gotze could make his 50th start in the Champions League in this match. He has been involved in 25 goals in his previous 65 appearances, including 21 in his 49 starts.
3 – Marseille have won their last two games in the Champions League – both against Sporting CP – and will be looking to win three in a row for the first time since October-December 2010, when they won four on the spin under Didier Deschamps.
Rumour Has It: Man Utd sanction £80m move for Kane to get the jump on transfer rivals
Harry Kane's future at Tottenham remains in limbo, given his contract status and the departure of Antonio Conte.
The 29-year-old forward, who recently became Spurs' all-time leading scorer, is out of contract in 2024.
Kane has previously spoken about his desire to contend for silverware and almost joined Manchester City in 2021.
TOP STORY – MAN UTD SANCTION KANE MOVE
The Manchester United bosses have sanctioned a potential £80million deal for Tottenham striker Harry Kane, reports the Daily Star.
United are ready to ramp up their interest in the England captain, who has interest from Bayern Munich, Barcelona and Chelsea.
The report claims United hope to get the jump on their rivals and open up talks soon, with a view to having a deal agreed with Kane within weeks.
ROUND-UP
– The Times reports Bayern Munich want to sign Chelsea midfielder Mason Mount who previously worked with the German champions' new boss Thomas Tuchel.
– Arsenal are circling for Eintracht Frankfurt's Danish midfielder Jesper Lindstrom who may be available for €30m, reports Sport1.
– The Mirror claims Liverpool have joined the battle to sign Evan Ndicka from Eintracht Frankfurt as a free agent in the off-season.
– Barcelona may cash in on Samuel Umtiti's revival on loan at Lecce and look to recoup a transfer fee this off-season according to SPORT.
– Sky Italy claims former Real Madrid boss and France World Cup winner Zinedine Zidane is on Tottenham's shortlist to replace Conte, along with Mauricio Pochettino, Julian Nagelsmann and Luis Enrique.
Rybakina wins 12th straight to reach Miami Open semi-finals, Pegula beats Potapova
Elena Rybakina is now two wins away from completing the rare 'Sunshine Double' after defeating Martina Trevisan 6-3 6-0 to reach the Miami Open semi-finals on Tuesday.
Only four women have ever claimed the Sunshine Double – which requires winning both the Indian Wells Open and Miami Open. Steffi Graf did it in both 1994 and 1996, Kim Clijsters did it in 2005, Victoria Azarenka accomplished the feat in 2016 and current world number one Iga Swiatek did it just 12 months ago.
Rybakina knocked off Swiatek and world number two Aryna Sabalenka in consecutive matches en route to the Indian Wells title, and she has now extended her winning streak to 12 with Tuesday's victory. Against Trevisan, Rybakina served another 10 aces compared to zero from the Italian.
In her fourth-round match the Kazakhstan representative became the first WTA player this season to post three consecutive matches with at least 10 aces, and with another she became the first woman since Serena Williams at the 2020 US Open to do so in four consecutive matches at the same tournament.
She needed just 27 minutes to race through the second set, and in the process she booked a semi-final against third seed Jessica Pegula.
America's top hope, Pegula had to come from behind against Russia's Anastasia Potapova in the 4-6 6-3 7-6 (7-2) result, saving two match points in the deciding set to force the pivotal tiebreaker.
The match was delayed for hours due to persistent rain, and the contest lasted two hours and 38 minutes, meaning they did not finish up on court until nearly 1:30am local time.
While consistently making it deep into major tournaments, Pegula only has two WTA singles titles to her name, and only once since the end of 2019.
With one more win she can book her spot in the final, and a chance to claim her second WTA 1000 crown after breaking through at the 2022 Guadalajara Open.
Messi hopes the 'craziness never ends' after 100th international goal and wild celebrations
Lionel Messi hopes the "craziness never ends" after scoring his 100th goal and ninth hat-trick for his country amid Argentina's homecoming World Cup celebrations on Tuesday.
La Albiceleste routed Curacao 7-0 in Santiago del Estero, with Messi's 20th-minute opener bringing up his 100th international goal, joining only Cristiano Ronaldo (122) and Ali Daei (109) in achieving that feat.
Messi became the first world champion to score 100 international goals, and he showed no signs of stopping there with further first-half strikes for a treble, taking him to 102.
The milestone came as Argentina rounded out their first two games back in their homeland since December's World Cup triumph with wild celebrations, initially in Buenos Aires for Thursday's 2-0 win over Panama.
The players emulated their celebrations from Qatar after the Curacao game, hoisting the World Cup trophy again after it came down from the stadium roof and doing a lap of honour to greet the supporters.
Messi was also presented with a plaque by Argentine Football Association president Claudio Tapia to acknowledge his 100th goal.
"What a nice way to close these dates, impressive today all the people in Santiago del Estero," Messi wrote on Instagram.
"I wish we can continue to share together many moments like these and that this craziness never ends!!!"
Messi's achievement comes after netting 21 goals in his 14 games for Argentina, along with seven assists. That has taken him to 156 goal contributions, which is the most in international football.
Argentina head coach Lionel Scaloni added: "As for Lionel Messi, what I want is for him to be on the pitch and be happy."
He added: "These days were different to the previous friendlies because the players were allowed to be with their people.
"We felt that they had that desire to go out to contact the outside, although that meant that it was difficult to prepare these two games. But in the end we got them through by playing with intensity."
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